“On the influence of changes in the CO2 concentration in air on the radiation balance of the Earth’s surface and on the climate”
The numerical value of a temperature change under the influence of a CO2 change as calculated by Plass is valid only for a dry atmosphere. Overlapping of the absorption bands of CO2 and H2O in the range around 15 μ essentially diminishes the temperature changes. New calculations give ΔT = + 1.5° when the CO2 content increases from 300 to 600 ppm. Cloudiness diminishes the radiation effects but not the temperature changes because under cloudy skies larger temperature changes are needed in order to compensate for an equal change in the downward long-wave radiation. The increase in the water vapor content of the atmosphere with rising temperature causes a self-amplification effect which results in almost arbitrary temperature changes, e.g. for constant relative humidity ΔT = +10° in the above mentioned case. It is shown, however, that the changed radiation conditions are not necessarily compensated for by a temperature change. The effect of an increase in CO2 from 300 to 330 ppm can be compensated for completely by a change in the water vapor content of 3 per cent or by a change in the cloudiness of 1 per cent of its value without the occurrence of temperature changes at all. Thus the theory that climatic variations are effected by variations in the CO2 content becomes very questionable.
Möller, F. (1963), On the influence of changes in the CO2 concentration in air on the radiation balance of the Earth’s surface and on the climate, J. Geophys. Res., 68(13), 3877–3886, doi:10.1029/JZ068i013p03877.
Bolded text above for emphasis is mine and not in original text.