The atmospheric concentration of CO2 gas is continuously adjusting to maintain the concentration partition ratio K derived in Henry’s law. Henry’s law partition ratio is independent of the source of the CO2. The net average atmospheric concentration of CO2 (~400 ppmv) is independent of human CO2 emission. Human CO2 is fully compensated in (and only a small part of) the natural global CO2 fluxes in the environment.
Ocean has been estimated to make up 98% of the hydrosphere. (Mason, 1958) Rainwater is less than 2% of the hydrosphere. Mason points out that ocean is 98% of the hydrosphere but he does not specify the rain portion, but he states that no significant error will be made by assuming the average CO2 concentration in all water is the average of sea water.
According to Henry’s Gas Law, the giant mass of CO2 gas in ocean water, on the order of 40,000 gigatonnes of carbon (4 X 1013 metric tonnes) and temperature regulate the atmospheric CO2 gas concentration and the CO2 fluxes in the atmosphere, ocean, biosphere and even in rainwater droplets. Approximately 1020 gigatonnes of CO2 in ocean surface in contact with about 750 gigatonnes of CO2 in air exchange about 90 gigatonnes of CO2 per year through the air/ocean surface per year. (See Carbon Cycle graphic below) Following Henry’s Law, the high solubility of CO2 gas in liquid water means the atmosphere is scrubbed of CO2 gas by the enormous volume of liquid water in the ocean, air and soil.
“The total CO2 produced by the burning of the annual production of coal and oil is 6.2 X 1015 g or about 1/300th of the amount in the atmosphere today. This might suggest that at the present rate of consumption of fossil fuels atmospheric carbon dioxide will be doubled in 300 years. However, in this connection the importance of the hydrosphere as a reservoir of carbon dioxide should be emphasized; its significance has been discussed by Revelle and Suess (1957). Sea water contains 20 g of CO2/cm2 of the earth’s surface, as against 0.4 g/cm2 in the atmosphere. Oceanic and atmospheric carbon dioxide are interdependent, the former being a function of the partial pressure of CO2 in the atmosphere. Thus to double the partial pressure of carbon dioxide in the atmosphere would require the addition of much more than is now present therein, because most of that added would be absorbed by the ocean; similarly to decrease the carbon dioxide in the atmosphere by half would require removal of many times the present content. It is apparent that the oceans, by controlling the amount of atmospheric CO2, play a vital part in maintaining stable condition suitable for organic life on the earth.” (Mason, Page 211-212.)
Note in the above quotation, the 50:1 ratio of grams of CO2 in sea water to grams of CO2 in atmosphere. (20 g of CO2/cm2 in sea water surface versus 0.4 g/cm2 CO2 in the atmosphere= 50:1 ratio). This partition ratio of CO2 gas between water and air is governed by Henry’s Gas Law. The absorption of CO2 gas into the surface of water is fast (sub-second) and driven primarily by water temperature. Colder water absorbs CO2. Warm water emits CO2 gas into the air. The distribution of CO2 gas horizontally and vertically in atmosphere and ocean water is not as fast, but these chaotic processes will not be discussed here.
The dissolution time of aqueous CO2 gas into its various dissolved carbonate forms is very fast (seconds.) The chemical reaction of carbonate ions with oceanic buffering systems is very fast (seconds.) The calcium buffering system of ocean will be discussed briefly as an example.
Absorption and emission of CO2 from the surface of water acts locally on every square centimeter of water surface every second. Normalizing temperature and CO2 concentration by averaging removes information and adds no value to the analysis. The temperature difference above and below about 26 C are the critical variables which define whether CO2 is being absorbed or emitted at a particular location and time. The temperature controls the direction of the flux. The temperature difference and surface area at that temperature control the amount and the velocity of the flow. All of that information is missing when only a global average temperature is used. “The average temperature of the ocean surface water is about 17 °C (62.6 F).” (Temperature of Ocean Water, University of Michigan. August 31, 2001.) The average temperature of ocean surface water is irrelevant to the Henry’s Law equilibrium and to the solubility chemistry of CO2 in water. The average of very large chaotic fluxes is a meaningless number with no predictive value.
In the graphic below we can easily see where CO2 is emitting into air and where CO2 is absorbing into ocean and soil. A global average temperature would tell us nothing. When temperature exceeds 26 C, CO2 will be emitted from water. When temperature is less than 26 C, CO2 will be absorbed into water. We can also infer from this graphic that there are enormous fluxes of atmospheric CO2 gas from the equator to higher latitudes near both poles. In fact there are many cells in the atmosphere and in the ocean each with its own CO2 flux.
At a few thousand meters altitude above sea level where water vapor and aerosols condense into liquid water droplets, and anywhere condensation occurs, the surface of water droplets will be either absorbing or emitting CO2 based dominantly on temperature. Henry’s law determines the solubility of CO2 gas in all water, not only in ocean water. The CO2 gas concentration in your beverage is changing in real time.
If the top of a can or bottle of a carbonated beverage is removed, or the beer is tapped from the keg into your glass, initially the CO2 gas concentration in the liquid beverage will immediately decline because the total pressure of the gases above the liquid is significantly less than the total pressure of the mixed gases above the liquid in the closed keg. After that, the aqueous CO2 gas concentration in your beverage will continue to decline until the liquid and air above it reach the Henry’s Law equilibrium partition ratio K, which is based primarily on the temperature of your beverage.
Addition of certain salts or acids to the liquid increases the aqueous CO2 gas concentration. Carbonated beverages typically contain a small amount of acid, for example phosphoric acid, to increase retention of aqueous CO2 gas in the liquid. Rain scrubs chemicals such as sodium chloride from the air which become ionic in raindrops and that in turn changes the aqueous CO2 gas concentration in raindrops.
Henry’s Law only applies to the solubility of gases into liquids when the gas concentrations are low. When they are low, such as rare gas CO2 at 400 parts per million, then concentration of CO2 gas in the liquid and in the air above the liquid can be calculated and measured with very high accuracy and precision. Henry’s Law is the basis of the multi-billion dollar per year scientific instrumentation industry of gas chromatography. GC’s are used routinely in almost all industries involving chemistry from perfumes to paint to healthcare to refineries.
Henry’s Law partition only applies to the gas phase in the liquid, for example aqueous CO2 gas in ocean, and the gas above the liquid, for example CO2 in the air. Aqueous CO2 gas reacts in seconds in water by disassociating into several forms of carbonate ions. These carbonate ions then react with ionic forms of other molecules which are also dissolved in ocean water, for example calcium ions. Calcium ions (Ca+2) react with a carbonate ions to form calcium carbonate (limestone, dolomite, CaCO3). This calcium carbonate precipitates as a solid and becomes slurry then stone on the sea floor. This disassociation chemistry is not determined by Henry’s Law. Ocean buffering systems such as this calcium chemistry are removing aqueous CO2 gas from the Henry’s Law equilibrium equation. This calcium buffering chemistry is very important to the concentration of CO2 in the ocean and atmosphere and is defined by other laws, as will be briefly mentioned.
A rain droplet falls through air containing CO2 gas. The CO2 gas partition ratio between the air and the rain droplet is adjusting in real time (no significant lag, no equilibrium) to the temperature differential experienced in the rain droplet as it falls and the CO2 concentration in the surrounding air. As the rain droplets fall to earth, in tropical and temperate latitudes when the droplet temperature exceeds 26 C, the droplets emit CO2 gas. In higher temperate and polar latitudes, when droplet temperatures are less than 26 C, the falling drops will be absorbing CO2 gas from the air as they fall.
Droplets of water nucleate on particles in the atmosphere. The types of particles vary widely based on geography. Salt and other minerals and gases are carried aloft by wind, currents, convection, storms over ocean. Oceans are ~70% of earth’s surface. Over land the chemical composition of raindrops is much more variable; no simple algorithm is possible. Rain droplet formation is discussed in detail in Professor Murry Salby’s text Physics of The Atmospheric and Climate, 2012.
The chemical composition of raindrops varies with the amount of rain falling during a given time period. Rain (and dew) scrub the air of particulates and gases, e.g., hydrocarbon gases. Hydrocarbon, sulfur and nitric gases are higher concentration in urban areas than over ocean, and these gases are found in raindrops in those areas, again obeying Henry’s Law K for each gas. The same is happening for CO2, methane, argon, and other gases found in air; each gas has its Henry’s Law solubility K for water. You have probably noticed that the air is cleaner after a good rain.
In general, wherever water temperature is below 26 C, that water is absorbing CO2 gas in real time, no delay, in proportion to the temperature difference above 26 C and in proportion to the area of water surface which is in contact with air at that temperature. Anywhere water temperature is above 26 C it will be emitting CO2 gas into air. Rain arriving at ocean surface changes the concentration of CO2 gas in ocean surface, which will then drive re-equilibration based on Henry’s Law partition ratio in that surface water.
Water droplets in clouds, falling from clouds, and condensing in air sum to a relatively high surface area compared to the flat 2 D surface area of the ocean. Approximately 4πr2 verses r2. Therefore, taken altogether, the additional sink and source due to raindrops would appear to be significant relative to other sinks and sources. But, building an algorithm to calculate the size of this additional rain sink and source would be as uncertain as predicting the weather, primarily due to variances driven by water in all its phases and chaotic conditions.
For example, in Hawaii near the northern boundary between temperate zone and tropical zone, rain and clouds are cooler than ocean surface. Raindrops have a larger ratio of surface area / volume ratio than ocean surface. Cooler raindrops temporarily increase the aqueous CO2 gas concentration in ocean surface water in Hawaii and all of the tropics. But since ocean water in the tropics is usually warmer than 26 degrees, that additional aqueous CO2 gas will be rapidly (seconds) emitted to atmosphere as the temperature of the cooler rainwater rapidly warms to the temperature of the ocean’s massive heat sink. Thus, raindrops are another large, chaotic CO2 gas flux between sink and source. It would be difficult or impossible to model with accuracy this chaotic bi-directional CO2 flux between sink and source.
To calculate how much CO2 is in rain, we would need to know the amount of precipitation that is liquid, the surface area of rain drops, the temperature gradients in the global atmosphere and ocean, of course Henry’s Law for myriad conditions, etc. Some of the needed information is measured and estimated. Volume of global precipitation is calculated by taking the product of the Earth’s surface area and its average annual rainfall. Total annual volume of precipitation of water in all phases is about 5.1 × 1014 m3. In other words, fossil fuel CO2 gas emission on the order of 5.5 X 109 metric tons (see graphic) is being absorbed into a volume of rain that is on the order of 1014cubic meters. Raindrops are a large sink and source for CO2 gas. Rain is scrubbing the air of CO2 just as it scrubs air of other gases and particles. Whether rain is a sink or source of CO2 depends on temperature in that location.
The following graphic of the carbon cycle is routinely provided by UN IPCC and other proponents of anthropogenic global warming. Notice that rain is not included. Also the graphic implies that the different CO2 sources and sinks are not connected. It also implies that fossil fuel emission is only emitted and not absorbed, implying that it remains in the atmosphere. However, in fact, these fluxes into air and into ocean are connected by Henry’s Law and other laws of chemistry and physics.
The Carbon cycle graphic above. The figures indicate carbon storage and flows, expressed in gigatonnes One gigatonne is 1,000 million metric tonnes of carbon or 1 billion metric tonnes. A tonne is a metric unit equal to 1000 kilograms or 106 grams. A gigatonne is 109 grams. One metric tonne equals 1.102 tons. A ton is non-metric old English or American unit sometimes called a short ton. A ton is 2000 pounds. A tonne is about 10% more than a ton. The arrows are proportionate to the volume of carbon. The figures for the flows express amounts exchanged annually. Year: 2009. From collection: Kick the Habit: A UN Guide to Climate Neutrality. Cartographer: GRID-Arendal. www.grida.no/resources/5390
Notice in carbon cycle graphic, CO2 gas in the ocean surface is about 1020 gigatonnes (1.020 X 1012 grams), while absorption into ocean surface is about 92 gigatonnes, (9.2 X 1010 grams) while the estimated fossil fuel CO2 emission into air is 5.5 gigatonnes (5.5 X 109 grams), but the implication of this graphic is that 5.5 gigatonnes of fossil fuel emission is not mixed with or absorbed by the environment. In fact, fossil fuel CO2 is immediately and continuously mixed with CO2 already in the environment, i.e., during a year about 5.5 gigatonnes of fossil fuel CO2 is mixed with about 92 gigatonnes of atmospheric CO2 and that mixed CO2 is also mixed continuously with 1020 gigatonnes of CO2 in ocean surface. The author/artist and global agencies and governments and AGW proponents clearly imply that CO2 emission from fossil fuel is a net addition of CO2 to the atmosphere; this is false. In fact, using numbers from their graphic, there is an immediate dilution of more than 16 times of CO2 (5.5 divided by 92) which is immediately and continuously diluted again by more than 10 times (5.5 + 92 = 97.5. Then 97.5 divided by 1020). In a ratio of about 50:1, atmospheric CO2 from all sources is being absorbed into ocean surface where water is cold and about 1 part in 50 is emitted into air where ocean surface water is warm, and both absorption and emission are happening in seconds simultaneously and continuously.
All of these amounts of CO2 gas shown in the atmosphere are soluble into an annual volume of water precipitation of about 5.1 × 1014 m3 Unfortunately we do not know the ratio of liquid water precipitation to solid water precipitation remaining as solid ice or snow. This is a rough estimate. A cubic meter equal 1000 liters. Annual water precipitation is about 5.1 X 1017 liters. Using the annual fossil fuel emission from the graphic above, 5.5 X 109 grams of CO2 is diluted into 5.1 X 1017 litersof water precipitation. 5.5 X 109 grams CO2 divided by 5.1 X 1017 liters of water equals a concentration of 1.08 X 10-8 grams of CO2 per liter of water. One gram per liter equals 1000 parts per million. 1.08 X 10-8 X103 = 1.08 X 10-5 parts per million. In sum, the estimated annual fossil fuel emission of 5.5 gigatonnes of CO2 is only about 0.000108 ppm in annual water precipitation. It appears that annual rain could easily absorb all annual fossil fuel CO2 emissions.
Since rain is generally colder than surrounding air and less than 26 C, and rain contains only about 0.000108 ppm of CO2, this strongly suggests that in general rain will be strongly absorbing CO2 from air in order to reach a Henry’s equilibrium of 2000 ppmv in water.
On average, rainwater itself has more than enough surface area and raindrops have a large CO2 concentration deficit. However, rain is notoriously difficult to predict, and absorption and emission are caused by local conditions, not global averages. However, the surface of the ocean is larger and ever present and more than sufficient to scrub all human-produced CO2 annually, and scrubbing by rain is additional to ocean. As mentioned above, ocean buffering systems are continuously removing aqueous CO2 gas from ocean water and producing limestone and other carbonate rock and sedimentation. Ocean has “an almost infinite buffering capacity” for CO2. (Segalstad, page 820. Stumm and Morgan; Segalstad and Jaworowski, 1991).
CO2 gas concentration in air and ocean is independent of human emission. (Salby). CO2 concentration in air is observed as the net residual difference between net emission of CO2 minus net absorption of CO2, that is about 400 ppmv. (Salby) That net residual difference is determined primarily by temperature changes in ocean and soil, according to Henry’s Law. Driven dominantly by temperature, all CO2 emissions from all CO2 sources are compensated by natural adjustment of the partition ratio of CO2 gas concentration in air versus the aqueous CO2 gas concentration in the surface of all water. This equilibration is occurring rapidly and continuously worldwide, where locations in northern latitudes will be absorbing CO2 and latitudes in or near the tropics are emitting CO2. Human CO2 emissions (~5.5 gigatonnes per year) into atmosphere are immediately diluted into an order of magnitude (more than 16 times) larger CO2 sink (~ 90 gigatonnes of CO2) in the atmosphere. Then, atmosphere in contact with ocean results in another order of magnitude (10 times) dilution into the 1020 gigatonne sink of CO2 gas in the surface of the ocean. Dilution into ocean surface begins immediately in seconds.
There is another significant dilution. As mentioned above, aqueous CO2 gas in ocean water (~ 2000 ppmv) is continuously diluted and removed from ocean and from the Henry’s Law equilibrium by rapid dissolution into the multiple vast inorganic ionic buffering systems in ocean water. (Mason. Segalstad. Stumm & Morgan.)
“The upper 200 m of ocean water contains enough dissolved calcium to bind all human produced Anthropogenic CO2 as precipitated calcium carbonate (in the ocean) without affecting the ocean’s pH (Jaworowski et al., 1992a; Segalstad, 1996; 1998).” (Segalstad, page 818)
This is only the calcium buffering system, one of several oceanic buffering systems. All human CO2 emission, not only one year’s emission but all human emission, could be dissolved in only the top 200 meters of ocean water by the calcium buffering system alone. (Segalstad) This follows from the relative abundance of the carbonate, calcium and hydroxyl ion reactants in the ocean buffering chemistry reactions.
In seawater, the Ca2+ ion is 2.9 times more concentrated than the carbonate (HCO3–) ion (0.4121 g/kg vs 0.1424 g/kg) (Stumm & Morgan). Dissolution into this calcium buffering system is very fast (seconds.) This is easily demonstrated by blowing bubbles through a straw into a water solution containing calcium hydroxide [Ca(OH)2 i.e., caustic lime] at its oceanic concentration. Within seconds, the CO2 in your breath forms a cloud of white calcium carbonate solid in the water and precipitates to the bottom of the container. The requirements for this precipitation are excess calcium ions and excess hydroxyl ions ( OH– ) ; ocean water surface has both. The hydroxy ion concentration is observed as the alkaline pH of ocean water. The same fast precipitation rate occurs in ocean water. This process continuously removes aqueous CO2 gas from ocean water, converting it through several intermediate ionic carbonates and then to solid precipitate stone thus continuously driving absorption of more CO2 gas into ocean water to maintain Henry’s Law partition between ocean and air. The ocean calcium buffering system is a gigantic, continuous CO2 sink. Limestone and similar carbonate rock are plating on ocean floor in mid-ocean depths controlled by temperature and water pressure at depth. Converting this solid carbonate stone back into atmospheric CO2 gas requires volcanic temperatures, a chemistry well known for centuries in production of cement by burning limestone which emits CO2 gas. Some “climate science” literature argues this ocean buffering chemistry operates in time frames of hundreds to thousands of years. That is only half true. The sink (absorption) side of this chemical reaction is ongoing continuously and happens in seconds. Only the source side (emission) of this chemistry, i.e., emissions from volcanic eruption processes, is long term.
“The Law of Mass Action ensures when all these chemical reactions have been accounted for in the total net reaction (and when increasing the amount of a gas, CO2, in the air), calcium carbonate (solid) will be stabilized in the ocean, because the chemical reaction will be forced in the direction from left to right. This result is the opposite of what is commonly asserted (that solid calcium carbonate would be dissolved by the increasing amount of CO2 in the air).” (Segalstad, page 819)
“The loss of carbon dioxide from the atmosphere by deposition as carbonate and organic carbon in sedimentary rock was estimated by Rubey as totaling 920 X 1020 g. More recently, Wickman (1956) has published some revised figures. He places the amount of carbonate carbon per square meter of earth’s surface as 2420 +/- 560 g and of organic carbon at 700 +/- 200 g. Taking the figure of 3100 g/m=cm2 for the total amount of carbon transferred from the atmosphere to the sedimentary rock, this is equal to a total of 158 X 1020 g of carbon, or 580 X 1020 g of CO2. This latter figure is of the same order of magnitude as Rubey’s but considerably lower. The figures show clearly that the amount of carbon dioxide deposited in sedimentary rocks far exceeds the amount in the present atmosphere, hydrosphere, and biosphere (about 1.5 X 1020 ), and thus indicate that large amounts of carbon dioxide must have been released from magmatic sources throughout geological time to maintain organic activity. Wickman’s figures show, in addition, that far more carbon dioxide has been removed as limestone and dolomite than as coal or other organic carbon.” (Mason, page 209)
All of the above CO2 sinks and sources turn over in months except the emission of CO2 from limestone and other carbonate rock. This monthly rate is inferred from NOAA Mauna Loa CO2 data. The large (two to four times) differences in the annual rates of change of slope (i.e., accelerations) which are observed are stated to be due to seasonal photosynthesis and ice cover differences between the northern and southern hemispheres. The zig-zag “sharks teeth” within-year changes in slope are about +3.5 to -7 to +3.5. These are the annual seasonal “sharks teeth” on the NOAA Mauna Loa CO2 slope (graphic below.) These rapid within year accelerations are compared to an average slope (1.5 ppmv per year to 2 ppmv per year depending on year) of the net global atmospheric CO2 concentration. A very, very large rate-compensated drain is inferred from within-year difference observed in the 400 ppmv residual of two gigatonne fluxes (CO2 emission and CO2 absorption). CO2 absorption accelerates then sharply decelerates then sharply accelerates again. These small changes in sign and acceleration are residual differences between two enormous (gigatonne) CO2 fluxes in opposite directions. The analogy is the temperature and area of the surface of water act as a temperature controlled adjustable-rate CO2 valve controlling the fluxes between ocean and air. Add more CO2 from any source and the system adjusts the rate in both time and volume to achieve Henry’s K partition… without regard to the source of the CO2. And vice versa.
Henry’s law partition is independent of the source of the CO2. The net average atmospheric concentration of CO2 (~400 ppmv) is independent of human CO2 emission. For example, during the 2020 corona virus pandemic, fossil fuel CO2 emission is estimated to have decreased by 20% to 30%. At the same time, net global average CO2 trend increased by about 2 ppmv for 2020, rather than decreasing, as observed by the NOAA lab on Mauna Loa and shown in the graphic above; this demonstrates that the net global average atmospheric concentration of CO2 is independent of human CO2 emission. The CO2 trend is a function primarily of temperature. This relationship is explained in detail including derivation of the equations in the video lecture at the link in the references below (Salby), Murry Salby, Professor of Atmospheric Physics and author of two texts on the subject.
On a time scale of millions of years, atmospheric CO2 has been in a steady declining trend. Ocean is absorbing CO2 from air, the aqueous CO2 gas ionizes, then reacts to produce limestone and other sediment and rock on the walls and floor of the ocean.
Any and all additional CO2 added to the air from any and all sources will enter the ocean surface and be balanced in an Henry’s Law equilibrium of approximately 50:1 ratio between water and air at the specific temperature in that location.
The graphic of net global average CO2 concentration, for example from the NOAA Keeling Laboratory on Mauna Loa in Hawaii above, is a graph of an equilibrium equation. The equation for the line on the graph is controlled by temperature. Temperature controls the ratio of the CO2 in the air versus the aqueous CO2 gas in water. The line on the graph is recording the points where the net global flux of CO2 into the air is in equilibrium with the net global flux into water in all its liquid forms at a specific temperature. If temperature is increasing, then relatively more CO2 is emitted from water into air. If temperature is decreasing, then more CO2 is absorbed into water.
An equilibrium equation which is a function of temperature is explained in this short video. Simply substitute CO2 where the professor has H2O as his example. In the case of CO2, temperature is driving the Henry’s Law equation for the ratio of CO2 gas in water versus CO2 gas in air.
The multiyear long term trend (or slope) in net global average CO2 concentration (NOAA Mauna Loa graphic above) is the result of slowly increasing surface temperature since the end of the last ice age.
Ocean surface is about 70% of the surface of the earth. The ocean is the lung of all life on earth, breathing out life-giving CO2, and breathing in life-giving CO2.
Carbon is the fundamental building block of life on earth, a major component molecule for every cell in all life forms on earth with exception of a few very rare bacteria in deep ocean volcanic vents and these rare bacteria still contain carbon. All of the carbon in all of your cells was at one time CO2 in the air. All of the carbon in every cell of every plant, animal, insect, fish, etc. was once CO2 gas in the air. The ONLY way that carbon gets into living things is by plants absorbing CO2 from the air for photosynthesis and then other living things eat those plants.
People and plans to reduce atmospheric CO2 are functionally a eugenics death cult which would, if successful, reduce sustainability of life on earth by resulting in less food and ultimately lower population of all living things. For example, plans by billionaires, governments and quasi governments to create artificial clouds to block the sun would intentionally cool ocean surface. As you now know from the discussion above, this would remove CO2 plant food from air and starve plants, crushing food supply for all life. Such plans to cool the planet could force rapid absorption of CO2 into ocean in amounts far in excess of the amount of CO2 produced by humans. If humans cool the surface and force the carbonate chemistry to the right, to more products and more stone, then life may never recover. It may be possible to geoengineer clouds to cool the oceans and force absorption of CO2. But when they discover the mistake, warming will be much more difficult or impossible. These are very dangerous geoengineering plans driven by ideology not science or common sense and if done or seriously attempted most likely humanity will have sealed its fate in stone.
During my seventy plus year lifetime, all of humanity has been buried by a non-stop, extremely well-funded propaganda campaign designed to convince people to feel guilty about their carbon footprint and to fear a never-ending list of climate catastrophes, all caused, so they claim or imply, by human-produced CO2. Their propaganda and funding has been accelerating since the 1960s following the required reading of “The Population Bomb” and “Ecoscience.” This mistaken ideology is based on the 18th century mistaken calculations of Thomas Malthus who believed that human population growth would exhaust earth’s natural resources. Although Malthus’ forecasts have never happened, including the fact that human population growth rate has been declining for decades, his ideology has been adopted by the wealthy, the influential, the UN and over 100 governments, academics and major corporations. Wittingly or not, they are driving what is in fact a globally destructive eugenics campaign financed by trillions of dollars. The pace and intensity of the propaganda campaign will accelerate as the date approaches for the next UN IPCC climate conference, as it always has. This is a dangerous, gigantic global fraud. “Stop treating it [i.e. AGW…human-caused global warming/climate change] as a worthy opponent. Do not ascribe reasonableness to the other side. It is not reasonable, not true, not even plausible.” ~ Richard Lindzen, Professor Emeritus, Alfred P. Sloan Professor of Meteorology, Massachusetts Institute of Technology. (31 March 2021. Zoom call Clintel Foundation)
(Salby) Lecture by Professor Murry Salby, PhD. https://youtu.be/b1cGqL9y548
(Mason) Mason, Brian. Principles of Geochemistry. 2rd Edition. 1958. https://archive.org/details/principlesofgeoc0000unse/page/212/mode/2up
(Segalstad) Segalstad, Tom. Some thoughts on ocean chemistry (Chapter 184.108.40.206). January, 2014. In book: Climate Change Reconsidered II – Biological Impacts. Page 818, 819. https://www.researchgate.net/publication/304797201_Some_thoughts_on_ocean_chemistry_Chapter_6312
Carbon cycle graphics: https://grid-arendal.maps.arcgis.com/apps/MapJournal/index.html?appid=a49488a79f6644c290f7e01a29f57fc7
(Stumm & Morgan) Stumm, Werner; Morgan, James J. aut. Aquatic chemistry : an introd. emphasizing chemical equilibria in natural waters. 1981. https://archive.org/details/aquaticchemistry00stum/page/566/mode/2up
Segalstad, T.V. and Jaworowski, Z. 1991. CO2 og globalt klima. Kjemi51: 13–15.
“Annual average global precipitation is approximately 1123 mm (gauge corrections considered), which is consistent with other reported values. (Chonka-PTT)” = 5.73 × 1014 m3 (Legates, David R., Cort J. Willmott. Mean seasonal and spatial variability in gauge-corrected, global precipitation. International Journal of Climatology 10(1990): 111-127.)
“Because Earth’s average annual rainfall is about 100 cm (39 inches), the average time that the water spends in the atmosphere, between its evaporation from the surface and its return as precipitation, is about 1/40 of a year, or about nine days.” Encyclopædia Britannica. Encyclopædia Britannica Online. 2008.
“The average annual precipitation of the entire surface of our planet is estimated to be about 1050 millimeters per year or approximately 88 millimeters per month.” Pidwirny, M. Global Distribution of Precipitation. Fundamentals of Physical Geography, 2nd Edition. 17 April 2008.
This paper is re-published here:
Loved this article. Wish I could find a way to make John Kerry read it.
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FYI, for the frustration of the Warmies who insist that increased atmospheric CO2 causes ocean acidification despite the temperature of the water increasing, this is useful:
Click to access chapter2.pdf
And if you haven’t already come across it, this is informative:
It is interesting to conjecture on the effect of extrapolating ECS and TCR out to 2025 – 2030.
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Excellent article, well done!
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Thanks Larry. Thanks for reading.
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